Download e-book for iPad: Applications of Porphyrinoids by Roberto Paolesse

By Roberto Paolesse

ISBN-10: 3662439964

ISBN-13: 9783662439968

ISBN-10: 3662439972

ISBN-13: 9783662439975

The sequence subject matters in Heterocyclic Chemistry offers severe experiences on current and destiny traits within the learn of heterocyclic compounds. total the scope is to hide themes facing all components inside heterocyclic chemistry, either experimental and theoretical, of curiosity to the final heterocyclic chemistry group. The sequence comprises subject comparable volumes edited via well known editors with contributions of specialists within the box. All chapters from issues in Heterocyclic Chemistry are released on-line First with someone DOI. In references, issues in Heterocyclic Chemistry is abbreviated as best Heterocycl Chem and pointed out as a journal.

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2 Synthetic Strategies and Early Reported Macrocycles . . . . . . . . . . . . . . . . . . . 3 Recent Synthesis of Carboranyl-Containing Porphyrin Derivatives . . . . . . . . . . . . 1 Symmetric Carboranyl-Porphyrins and Chlorins . . . . . . . . . . . . . . . . . . . 2 Unsymmetric Carboranyl-Porphyrins and Chlorins . . . . . . . . . . . . . . . . . . 3 Carboranyl-Containing Corroles and Phthalocyanines .

References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . K. H. K. H. Vicente 1 Introduction Boron neutron capture therapy (BNCT) is a binary therapy that involves the irradiation of 10B-containing tumors with low energy thermal neutrons [1–4]. 4 MeV of kinetic energy, as shown in Fig. 1. The high-LET particles produced during the fission reaction have limited path lengths in tissue (5–9 μm), therefore making BNCT a localized form of treatment, able to destroy 10 B-containing malignant cells in the presence of 10B-free healthy cells.

Vicente MGH, Wickramasinghe A, Nurco DJ et al (2003) Synthesis, toxicity and biodistribution of two 5,15-di[3,5-(nido-carboranylmethyl)phenyl]porphyrins in EMT-6 tumor bearing mice. Bioorg Med Chem 11:3101–3108 55. Vicente MGH, Gottumukkala V, Wickramasinghe A et al (2004) Singlet oxygen generation and dark toxicity of a nido- and a closo-carboranylporphyrin. Proc SPIE 5315:33–40 56. Easson MW, Fronczek FR, Jensen TJ, Vicente MGH (2008) Synthesis and in vitro properties of trimethylamine- and phosphonate-substituted carboranylporphyrins for application in BNCT.

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Applications of Porphyrinoids by Roberto Paolesse


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